Publications of the Asymhole Project

  1. Groslambert, L.; Cornaton, Y.; Ditte, M.; Aubert, E.; Pale, P.; Tkatchenko, A.; Djukic, J.-P. Mamane, V. Affinity of Telluronium Chalcogen Bond Donors for Lewis Bases in Solution: A Critical Experimental-Theoretical Joint Study. Chem. Eur. J. 2024, 30, e202302933.
  2. Pale, P.; Mamane, V. Chalcogen bonding catalysis: tellurium, the last frontier? Chem. Eur. J. 2023, 29, e202302755.
  3. Sechi, B.; Dessì, A.; Dallocchio, R.; Tsetskhladze, N.; Chankvetadze, B.; Pérez-Baeza, M.; Cossu, S.; Jibuti, G.; Mamane, V.; Peluso, P. Unravelling dispersion forces in liquid-phase enantioseparation. Part I: Impact of ferrocenyl versus phenyl groups. Anal. Chim. Acta 2023, 1278, 341725.
  4. Weiss, R.; Aubert, E.; Groslambert, L.; Pale, P.; Mamane, V. Evidence for and evaluation of fluorine–tellurium chalcogen bonding. Chem. Sci. 2023, 14, 7221.
  5. Groslambert, L.; Padilla-Hernandez, A.; Weiss, R.; Pale, P.; Mamane, V. Chalcogen-Bond Catalysis: Telluronium-Catalyzed [4+2]-Cyclocondensation of (in situ Generated) Aryl Imines with Alkenes. Chem. Eur. J. 2023, 29, e202203372 (Hot Paper)
  6. Pale, P.; Mamane, V. Chalcogen Bonds: How to Characterize Them in Solution? ChemPhysChem 2023, 24, e202200481 (Concept Article)
  7. Dallocchio, R; Dessì, A.; Sechi, B.; Chankvetadze, B.; Jibuti, G.; Cossu, S.; Mamane, V.; Peluso, P. Enantioseparation of planar chiral ferrocenes on cellulose-based chiral stationary phases: Benzoate versus carbamate pendant groups. Electrophoresis 2023, 44, 203
  8. Peluso, P.; Mamane, V. Stereoselective Processes Based on σ-Hole Interactions. Molecules 2022, 27, 4625
  9. Sechi, B.; Dessi, A.; Gatti, C.; Dallocchio, R.; Chankvetadze, B.; Cossu, S.; Mamane, V.; Pale, P.; Peluso, P. Unravelling functions of halogen substituents in the enantioseparation of halogenated planar chiral ferrocenes on polysaccharide-based chiral stationary phases: experimental and electrostatic potential analyses. J. Chromatogr. A 2022, 1673, 463097
  10. Weiss, R.; Aubert, E.; Groslambert, L.; Pale, P.; Mamane, V. Chalcogen Bonding with Diaryl Ditellurides: Evidence from Solid State and Solution Studies. Chem. Eur. J. 2022, 28, e202200395 (Hot Paper, Cover picture: https://doi.org/10.1002/chem.202201065)
  11. Aubert, E.; Doudouh, A.; Wenger, E.; Sechi, B.; Peluso, P.; Pale, P.; Mamane, V. Chiral Ferrocenyl–Iodotriazoles and –Iodotriazoliums as Halogen Bond Donors. Synthesis, Solid State Analysis and Catalytic Properties. Eur. J. Inorg. Chem. 2022, 2022, e202100927

Other Publications (Since 2021)

  1. Sechi, B.; Mamane, V.; Dallocchio, R.; Dessi, A.; Cossu, S.; Jibuti, G.; Peluso, P. Enantioseparation of new axially chiral carboxylic acids on polysaccharide based chiral stationary phases under normal phase elution conditions. J. Pharm. Biomed. Anal. Open 2023, 1, 100011.
  2. Peluso, P.; Mamane, V. Ferrocene derivatives with planar chirality and their enantioseparation by liquid-phase techniques. Electrophoresis 2023, 44, 158
  3. Weiss, R.; Cornaton, Y.; Khartabil, H.; Groslambert, L.; Hénon, E.; Pale, P.; Djukic, J.-P.; Mamane, V. Deciphering the Role of Noncovalent Interactions in the Conformations of Dibenzo-1,5-dichalcogenocines. ChemPlusChem 2022, 87, e202100518 (Cover picture: https://doi.org/10.1002/cplu.202200044).
  4. Peluso, P.; Dallocchio, R.; Dessì, A.; Sechi, B.; Chankvetadze, B.; Cossu, S.; Mamane, V.; Aubert, E.; Rozzo, C.; Palmieri, G.; Spissu, Y. Exploring interaction modes between polysaccharide-based selectors and biologically active 4,4’-bipyridines by experimental and computational analysis. J. Chromatogr. Open 2022, 2, 100030.
  5. Dessì, A.; Sechi, B.; Dallocchio, R.; Chankvetadze, B.; Pérez-Baeza, M.; Cossu, S.; Mamane, V.; Pale, P.; Peluso, P. Comparative enantioseparation of planar chiral ferrocenes on polysaccharide-based chiral stationary phases. Chirality 2022, 34, 609-619.
  6. Weiss, R.; Aubert, E.; Pale, P.; Mamane, V. Chalcogen-Bonding Catalysis with Telluronium Cations. Angew. Chem. Int. Ed. 2021, 60, 19281.
  7. Weiss, R.; Golisano, T.; Pale, P.; Mamane, V. Insight into the Modes of Activation of Pyridinium and Bipyridinium Salts in Non-Covalent Organocatalysis. Adv. Synth. Catal. 2021, 363, 4779.
  8. Peluso, P.; Dessì, A.; Dallocchio, R.; Sechi, B.; Gatti, C.; Chankvetadze, B.; Mamane V.; Weiss, R.; Pale, P.; Aubert, E.; Cossu, S. Enantioseparation of 5,5’-dibromo-2,2’-dichloro-3-selanyl-4,4’-bipyridines on polysaccharide-based chiral stationary phases: exploring chalcogen bonds in liquid-phase chromatography. Molecules 2021, 26, 221.
  9. Aubert, E.; Wenger, E.; Peluso, P.; Mamane, V. Convenient access to functionalized non-symmetrical atropisomeric 4,4’-bipyridines. Compounds 2021, 1, 58.
  10. Dallocchio, R.; Sechi, B.; Dessì, A.; Chankvetadze, B.; Cossu, S.; Mamane V.; Weiss, R.; Pale, P.; Peluso, P. Enantioseparations of polyhalogenated 4,4’-bipyridines on polysaccharide-based chiral stationary phases and molecular dynamics simulations of selector–selectand interactions. Electrophoresis 2021, 42, 1853.
  11. Richard, J.; Joseph, J.; Wang, C.; Ciesielski, A.; Weiss, J.; Samorì, P.; Mamane, V.; Wytko, J. A. Functionalized 4,4′-Bipyridines: Synthesis and 2D Organization on Highly Oriented Pyrolytic Graphite. J. Org. Chem. 2021, 86, 3356.

Publications related to the AsymHole project (before 2021)

Solid State

  1. Abboud, M.; Mamane, V.; Aubert, E.; Lecomte, C.; Fort, Y. Synthesis of polyhalogenated 4,4′-bipyridines via a simple dimerization procedure. J. Org. Chem. 2010, 75, 3224.
  2. Abboud, M.; Kadimi, A.; Mamane, V.; Aubert, E. Conformational disorder in 4-(5,5′-dibromo-2′-chloro-[4,4′]bipyridinyl-2-yl)-benzaldehyde: role of π–π and halogen interactions. Acta Crystallogr., Sect. C 2010, C66, o381.
  3. Abboud, M.; Mamane, V.; Aubert, E. Energetic analysis of the molecular packing of 5,5′-dibromo-2,2′-bis[4-(methylsulfanyl)phenyl]-4,4′-bipyridine: the role of π-π and halogen interactions. Acta Cryst., C 2013, 69, 56.
  4. Mamane, V.; Peluso, P.; Aubert, E.; Cossu, S.; Pale, P. Chiral hexahalogenated 4,4′-bipyridines. J. Org. Chem. 2016, 81, 4576.
  5. Aubert, E.; Abboud, M.; Doudouh, A.; Durand, P.; Peluso, P.; Ligresti, A.; Vigolo, B.; Cossu, S.; Pale, P.; Mamane, V. Silver(I) coordination polymers with 3,3’,5,5’-tetrasubstituted 4,4’-bipyridine ligands: towards new porous chiral materials. RSC Adv. 2017, 7, 7358.

HPLC on Chiral Stationary Phase

  1. Peluso, P.; Mamane, V.; Aubert, E.; Cossu, S. Insights into the impact of shape and electronic properties on the enantioseparation of polyhalogenated 4,4′-bipyridines on polysaccharide-type selectors. Evidence of stereoselective halogen bonding interactions. J. Chromatogr. A 2014, 1345, 182.
  2. Peluso, P.; Mamane, V.; Aubert, E.; Dessì, A.; Dallocchio, R.; Dore, A.; Pale, P.; Cossu, S. Insights into halogen bond-driven enantioseparations. J. Chromatogr. A 2016, 1467, 228.
  3. Peluso, P.; Mamane, V.; Dallocchio, R.; Dessì, A.; Villano, R.; Sanna, D.; Aubert, E.; Pale, P.; Cossu, S. Polysaccharide-based chiral stationary phases as halogen bond acceptors: a novel strategy for detection of stereoselective s-hole bonds in solution. J. Sep. Sci. 2018, 41, 1247.
  4. Dallocchio, R.; Dessì, A.; Solinas, M.; Arras, A.; Cossu, S.; Aubert, E.; Mamane, V.; Peluso, P. Halogen bond in high-performance liquid chromatography enantioseparations: Description, features and modelling. J. Chromatogr. A 2018, 1563, 71.
  5. Peluso, P.; Gatti, C.; Dessì, A.; Dallocchio, R.; Weiss, R.; Aubert, E.; Pale, P.; Cossu, S.; Mamane, V. Enantioseparation of fluorinated 3-arylthio-4,4’-bipyridines: Insights into chalcogen and π-hole bonds in high-performance liquid chromatography. J. Chromatogr. A 2018, 1567, 119.
  6. Peluso, P.; Mamane, V.; Dessì, A.; Dallocchio, R.; Aubert, E.; Gatti, C.; Mangelings, D.; Cossu, S. Halogen bond in separation science: a critical analysis across experimental and theoretical results. J. Chromatogr. A 2020, 1616, 460788.

Medicinal Chemistry

  1. Dessì, A.; Peluso, P.; Dallocchio, R.; Weiss, R.; Andreotti, G.; Allocca, M.; Aubert, E.; Pale, P.; Mamane, V.; Cossu, S. Rational design, synthesis, characterization and evaluation of iodinated 4,4’-bipyridines as new transthyretin fibrillogenesis inhibitors. Molecules 2020, 25, 2212.

Theoretical Calculations

  1. Gatti, C.; Dessì, A.; Dallocchio, R.; Mamane, V.; Cossu, S.; Weiss, R.; Pale, P.; Aubert, E.; Peluso, P. Factors Impacting σ- and π-Hole Regions as Revealed by the Electrostatic Potential and Its Source Function Reconstruction: The Case of 4,4′-Bipyridine Derivatives. Molecules 2020, 25, 4409.

Catalysis

  1. Weiss, R.; Aubert, E.; Peluso, P.; Cossu, S.; Pale, P.; Mamane, V. Chiral Chalcogen Bond Donors Based on the 4,4’-Bipyridine Scaffold. Molecules 2019, 24, 4484.
  2. Mamane, V.; Peluso, V.; Aubert, E.; Weiss, R.; Wenger, E.; Cossu, S. Pale, P. Disubstituted Ferrocenyl Iodo- and Chalcogenoalkynes as Chiral Halogen and Chalcogen Bond Donors. Organometallics 2020, 39, 3936..